Abstract
AbstractBoronate esters that contain N‐donor groups are self‐complementary structures, which can assemble by means of dative boron–nitrogen bonds to form macrocycles or polymers. Herein, we describe the synthesis of dioxaborinanes and benzodioxaboroles containing pyridyl side chains. In the solid state, the dioxaborinanes were found to exist predominantly as monomers. Upon crystallization, aggregation into one‐dimensional polymers was observed, but only for boronate esters that contained electron‐withdrawing groups. The more Lewis acidic benzodioxaboroles, on the other hand, were found to form macrocycles both in solution and in the solid state.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
