Abstract
Processes of mild template synthesis occurring in systems 3d-element ion MII—(N,S)-, (N,O,S)-ambidentate ligson A—monoor dicarbonyl ligson B in gelatin-immobilized matrices are considered and discussed. The chemical nature of the final products of template synthesis formed under these specific conditions is compared with the chemical nature of the final products formed by template synthesis in solutions. In many cases, the nature and chemical composition of the products differ substantially. Specific features of the DFT calculated molecular structures of the macrocyclic compounds that could be formed due to the template synthesis in the systems indicated above are discussed.
Published Version
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