Abstract
A novel unsymmetrically substituted hydroxy-functionalized Zn ( II ) phthalocyanine (Pc) 1, bearing long aliphatic chains, namely, dodecyloxy units, has been designed and synthesized to investigate the influence of the terminal hydroxyl group on the formation of self-assembled nanostructures. The symmetric derivative, octadodecyloxy- Zn ( II ) Pc (2) has been also synthesized and used as reference compound for comparison purposes. The supramolecular organization of the Pcs has been carried out by spin-coating on a highly ordered pyrolytic graphite (HOPG) surface and has been investigated by atomic force microscopy (AFM) and scanning electron microscopy (STM). AFM and STM studies showed that unsymmetrically substituted hydroxy-functionalized Zn ( II ) Pc 1 gives rise to the formation of wire-like structures in different lengths from nanometer to micrometer scales, whereas in the case of the symmetrical Zn ( II ) Pc 2 the formation of the wires on HOPG was less pronounced.
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