Self-Assembled Nanofibrous Membranes by Electrospinning as Efficient Dye Photocatalysts for Wastewater Treatment.

Abstract

Water pollution has become a leading problem due to industrial development and the resulting waste, which causes water contamination. Different materials and techniques have been developed to treat wastewater. Due to their self-assembly and photocatalytic behavior, membranes based on graphene oxide (GO) are ideal composite materials for wastewater treatment. We fabricated composite membranes from polylactic acid (PLA) and carboxylic methyl cellulose (CMC)/carboxyl-functionalized graphene oxide (GO-f-COOH) using the electrospinning technique and the thermal method. Then, a nanofibrous membrane (PLA/CMC/GO-f-COOH@Ag) was produced by loading with silver nanoparticles (Ag-NPs) to study its photocatalytic behavior. These membranes were characterized using Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) in order to investigate the behavior of the fabricated membranes. The degradation kinetics studies were conducted using mathematical models, such as the pseudo first- and second-order models, by calculating their regression coefficients (R2). These membranes exhibited exceptional dye degradation kinetics. The R2 values for pseudo first order were PCGC = 0.983581, PCGC@Ag = 0.992917, and the R2 values for pseudo second order were PCGC = 0.978329, PCGC@Ag = 0.989839 for methylene blue. The degradation kinetics of Rh-B showed R2 values of PCGC = 0.973594, PCGC@Ag = 0.989832 for pseudo first order and R2 values of PCGC = 0.994392, PCGC@Ag = 0.998738 for pseudo second order. The fabricated nanofibrous membranes exhibited a strong π-π electrostatic interaction, thus providing a large surface area, and demonstrated efficient photocatalytic behavior for treating organic dyes present in wastewater. The fabricated PLA/CMC/GO-f-COOH@Ag membrane presents exceptional photocatalytic properties for the catalytic degradation of methylene blue (MB) dye. Hence, the fabricated nanofibrous membrane would be an eco-friendly system for wastewater treatment under catalytic reaction.