Abstract
Self-ignition of stoichiometric airlike argon mixtures of monocyclic and bicyclic small-ring hydrocarbons was investigated behind reflected shock waves at 1200–1600 K and 0.6 ± 0.1 MPa. The reactivity of small-ring hydrocarbons has been found to be determined by the properties of their thermal decomposition products. New high-temperature decomposition channels for spiropentane, methylenecyclobutane, and methylenecyclopropane have been discovered.
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