Self-alkali-activated self-cementation achievement and mechanism exploration for the synergistic treatment of the municipal solid waste incineration fly ashes and the arsenic-contaminated soils

Abstract

The feasibility and potential mechanisms of the self-alkali activation brought by municipal solid waste incineration (MSWI) fly ashes to the self-cementation of arsenic-contaminated soils were quantitatively evaluated and comprehensively analyzed to avoid the additional application of the alkali activators and binder materials traditionally. The employment of the two kinds of precursor materials achieved the self-alkali-activated self-cementation (‘double self’) under ambient conditions. The largest compressive strength (MPa) of 25.64 and lowest leaching toxicities (mg/L) of 21.05, 2.86, 0.08, 0.02, 2.05, and 0.34 for Zn, Cu, Cr, Cd, Pb, and As were obtained in the solidified matrix. Geopolymerization kinetics of the ‘double self’ cementation can be mathematically fitted by the Johnson-Mehl-Avrami–Kolmogorov model. CaClOH and halite in the MSWI fly ashes set up the self-alkali activation by reacting with the kaolinite and quartz in soils contaminated with arsenic by forming layered hydration and three-dimensional geopolymerization products to push for self-cementation.