Abstract
Herein, we present the syntheses of a novel coordination polymer (CP) based on the perylene-3,4,9,10-tetracarboxylate (pery) linkers and sodium metal ions. We have chosen sodium metal center with the aim of surmising the effect that the modification of the metal ion may have on the relative humidity (RH) experimental measurements of the material. We confirm the role of the ions in the functionalization of the deposited layer by modifying their selectivity towards moisture content, paving the way to the generation of sensitive and selective chemical sensors.
Highlights
Water vapor is present in the air and is the most varied component
Coordination polymers (CPs), including metal–organic frameworks (MOFs), are a relatively new class of materials that have attracted great interest due to their structural and topological diversity, as well as the properties that arise from their structural features [5,6,7,8]
We present a new coordination polymer (CP) based on the perylene derivative ligand and method to preserve material, and the the temperature was alsotoanalyzed
Summary
Water vapor is present in the air and is the most varied component. At the same time, atmospheric conditions are essential for many processes of our daily life, especially in an industry environment [1]. Coordination polymers (CPs), including metal–organic frameworks (MOFs), are a relatively new class of materials that have attracted great interest due to their structural and topological diversity, as well as the properties that arise from their structural features [5,6,7,8]. This class of materials has been used for RH sensors, as shown in [9], where a MOF is used to create a luminescent and impedance spectroscopy sensor. In [10], a luminescent RH based on MOF polymer is presented
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