Abstract
In real day scenario, it is an urge to provide a single solution of multiple problems. In this regard, herein rapid, selective and highly efficient chromo-fluorogenic detection of ammonia/aliphatic amines over aromatic amines has been investigated by means of a novel “opto-electronic nose”, CN-2, synthesized in a single-step via multiple inter/intramolecular C-N fusion reactions. The in-situ generated mono-protonated CN-2 can selectively detect primary to secondary to even tertiary aliphatic amines over aromatic amines within ∼40 S with extremely low detection threshold values of 27.2 ppb, 0.7 ppm, 5.4 ppm, 1.7 ppm from UV–Vis and 42.5 ppb, 1.61 ppm, 5.5 ppm, 6.14 ppm from fluorescence spectral data for NH3, hydrazine (primary amine), diethanolamine (secondary amine) and triethylamine (tertiary amine) respectively with the hypsochromic shift in the UV–Vis spectra along with fluorescence attenuation via target-specific deprotonation. The colorimetric signal can also be examined by Smartphone APP, which is well correlated with spectrophotometric outcomes. Interestingly, due to presence of a unique protonated antenna centre CN-2 with anti-oxidant activity can also detect aliphatic biogenic amines, like putrescine, spermidine, which are frequently released from spoiled food. Therefore, it may be exploited as smart food-spoilage indicator in real-time. Again, the aliphatic biogenic amines recognition capability from human urine made it as a potential prostate cancer biomarker sensor for clinical use, which alleviates the need of biopsies. CN-2 could also be employed towards one-to-two decoder logic-circuitry formulation to monitor the ammonia levels. Moreover, CN-2-functionalized hydrogel-membrane based portable, handy prototype could be utilized for easy on-site recognition of amine vapour. Reversible sensing behaviour in presence of HCl enables CN-2 to exhibit anti-counterfeiting activity. To the best of our knowledge, this is the first all-in-one phenazine-based Smartphone-assisted chromo-fluorogenic-chemosensor, which would be of enormous interest in food-packaging industry, information technology as well as in early-stage-cancer diagnosis.
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