Abstract

We propose a novel method for realizing the selective-area growth (SAG) of GaAs using metal gallium, instead of carbon-containing group-III sources, such as trimethylgallium (TMGa). In order to eliminate the growth of GaAs on a SiO 2 mask, trisdimethylaminoarsine (As[N(CH 3) 2] 3, TDMAAs) was used as an arsenic source. The growth of GaAs on SiO 2 was suppressed by increasing the substrate temperature and the TDMAAs beam-equivalent pressure (BEP). SAG was achieved at substrate temperatures of 550°C and higher. A smooth surface with a (2 × 4) reconstruction was obtained under a specific TDMAAs BEP. The epitaxial growth rate of GaAs decreased along with increasing the TDMAAs BEP; eventually, etching of GaAs by TDMAAs occurred at 600°C. The results show that SAG takes place due to the effect of an active species derived from TDMAAs on the re-evaporation of Ga adatoms from SiO 2.

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