Abstract

We review nuclear magnetic resonance (NMR) studies of secondary relaxation processes in glasses. The main focus is work on molecular glasses, where the secondary relaxation is usually associated with spatially highly restricted motion. We show that NMR is well suited to study such highly hindered motion when the spatial resolution of the standard echo techniques is improved. The NMR results are discussed in the framework of findings from other experimental techniques so as to provide a comprehensive picture of secondary relaxation processes in glasses.

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