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https://doi.org/10.1016/s0040-4039(00)94446-0
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Cite Journal: Tetrahedron Letters |  Publication Date: Jan 1, 1990 |
 Citations: 5 |
Affiliation: Inha University
Addition of phenyl radical to benzyl isocyanides gives benzonitrile and benzyl radicals, exhibiting positive Hammett γ = 0.26 and notable secondary α-deuterium kinetic isotope effects. These can be rationalized by concerted bond formation/cleavage occurring with polar transition states(TS).
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