Abstract
Salts of [Fe III(sal 2-trien)] +and [Fe II(phen) 3] 2+ cations and M[(dcbdt) 2] − anions with M = Ni and Au (dcbdt = dicyanobenzenedithiolate) with formula [Fe(sal 2-trien)] [M(dcbdt) 2] and [Fe(phen) 3] [M(dcbdt) 2] 2 were obtained and characterized by single X-ray diffraction and magnetic measurements. None of these salts shows a clear spin crossover behaviour and their magnetic properties are due essentially to the cations in a high spin S = 5/2 and low spin states for the Fe III and Fe II salts respectively. The magnetic Ni sublattices in both compounds appear to have a negligible direct contribution to the magnetization but enhance the AF interactions in the cation sublattice.
Published Version
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