Screening of pharmaceuticals and personal care products in the water environment of a region diversified in land use and urban development (Silesian Province, southern Poland)

Abstract

This research aimed to assess the PPCP contamination of the water environment within the Silesian Province (southern Poland), where emerging contaminants are likely to occur due to urbanisation and industrialisation, especially in the central part of the voivodeship. An attempt was made to compare the PPCP occurrence in waters of areas that varied in land use and urban development, i.e. within the Upper Silesian Urban Area (USUA) and outside this region. The research was performed in selected areas of the province and involved sampling of raw and treated wastewater from four wastewater treatment plants (WWTPs), as well as surface water (9 samples) and groundwater (14 samples) in six pilot sites. In total, 102 PPCPs were analysed using the LC-MS/MS method. In the natural waters, physicochemical parameters were also measured, and the basic chemical composition of the samples was determined. In the wastewater samples, the number of detected substances and the total PPCP concentrations were up to 66 PPCPs and 1211.0 µg/L in influents, and up to 59 PPCPs and 174.1 µg/L in effluents. The values for the natural water samples were respectively up to 71 PPCPs and 172.2 µg/L in surface water, and up to 13 PPCPs and 1.5 µg/L in groundwater. The results revealed that wastewater discharges from WWTPs using conventional treatment methods serve as a significant source of PPCPs due to inefficient removal of the microcontaminants. The contamination level of the surface waters in terms of the PPCP occurrence and basic chemical composition was higher within the USUA, where rivers are recipients of wastewater discharges from WWTPs. The PPCP quantity in the groundwater samples did not vary greatly within and outside the USUA, likely due to hydraulic connection between rivers and aquifers or induced surface water infiltration that recharge aquifers in some of the selected areas.