Scalable photoelectrochromic glass of high performance powered by ligand attached TiO2 photoactive layer

Abstract

A scalable photoelectrochromic (PEC) glass which can be darkened on exposure to sunlight and return to its original clear state in the absence of sunlight without any expensive materials like ruthenium dye or transparent conductive oxide was fabricated. The PEC glass is composed of light absorbing layer of ligand attached titanium oxide, color changing layer of tungsten oxide and the electrolyte containing redox mediator. This work reports, for the first time, on an application of salicylic acid attached TiO2 photoactive layer for PEC devices. The applicability of various salicylic acid derivatives attached TiO2 films in PEC device is individually investigated in dye solar cells. Among various salicylic acid derivatives studied, 5-methylsalicylic acid showed the best performance in terms of charge generation for coloration of WO3. By using 5-methylsalicylic acid instead of ruthenium dye, lower cost, higher stability, and simpler electrolyte composition have been realized. The changes in transmittance for coloration (ΔTC) depend on the thickness of WO3 and TiO2 in this device. Thus, we changed the thickness of WO3 and TiO2 to get the highest variation of transmittance for coloration. The preliminary optimization of PEC device exhibits ΔTC of 40.8% at 550 nm, the wavelength most sensitive to the human eye, and of 64.3% at 700 nm.