Salinity variation of formation water and diagenesis reaction in abnormal pressure environments

Abstract

An understanding to the chemistry of formation waters in sedimentary basins is important for many geological processes, such as the fluid-rock interaction, the migrating paths of fluid and the entrapment mechanisms of hydrocarbon. This paper deals with the salinity variation of formation water and diagenesis reaction in the abnormally pressured system. The Shiwu depression of the Songliao basin and the Yinggehai basin are selected for case studies. The studies indicate that there is a distinct difference in the chemistry of subsurface water between hydropressured and abnormally pressured systems. The Shiwu depression of the Songliao basin is composed of terrigeneous clastics in fluvial-lacustrine environments, which contain brackish water with salinity ranging from less than 1000 mg/L to 12000 mg/L. Water composition varies with depth and hydrochemical regions. In the underpressured strata deposited during the rifting period, the formation water is characterized by CaCl2 type water with high salinity. NaHCO3-dominanted water with lower salinity occurs at the hydropressured strata deposited during the post-rifting period. In this halite-free basin, brackish water may be attributed to the condensation of meteoric water and water-rock interaction. In the deeply buried underpressured water, a predominated diagenesis reaction resulting in enrichment of Ca and Cl and reduction of Na may be related to the albitization of plagioclase following the basinal fluid line (BFL). The Yinggehai basin constitutes clastic deposits in nearshore, neritic, shelf environments and contains brackish and saline water with salinity ranging from less than 15000 mg/L to 50000 mg/L. Pore water in these marine deposits must have originated from seawater. In the overpressured system, however, the formation water has much lower salinity and ion concentrations (except bicarbonate and carbonate) than normal seawater. The low salinity indicates that interstitial connate seawater is diluted by the water released from the transformation of smectite to illite. High bicarbonate and carbonate concentrations may contribute to mineral dehydration and kerogen-cracking reactions. Furthermore, low salinity water also occurs near and above the top of the geopressured zone in the diapiric structures, which may indicate that pore water with normal seawater salinity has been mixed by fresher saline water from deeper portions of the overpressured stratigraphic section.