Rydberg states of atoms and molecules. Basic group theoretical and topological analysis

Abstract

Rydberg states of atoms and molecules are studied within the qualitative approach-based primarily on topological and group theoretical analysis. The correspondence between classical and quantum mechanics is explored to apply the results of qualitative (topological) approach to classical mechanics developed by Poincaré, Lyapounov and Smale to quantum problems. The study of the action of the symmetry group of the problems considered on the classical phase space enables us to predict qualitative features of the energy level patterns for quantum Rydberg operators.