Abstract
Ruthenium-catalyzed hydrosilylation of alkynes was applied to hydrooligosilanes to furnish alkenyloligosilanes without Si–Si bond cleavage in good yields. The (E)- and α-adducts were obtained regio- and stereoselectively by using RuHCl(CO)(PPh3)3 and [Cp*RuCl2]n as catalysts, respectively.
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