Abstract

The rotational spectrum of the CO-para-H2 van der Waals complex, produced using a molecular jet expansion, was observed with two different techniques: OROTRON intracavity millimeter-wave spectroscopy and pulsed Fourier transform microwave spectroscopy. Thirteen transitions in the frequency range from 80 to 130 GHz and two transitions in the 14 GHz region were measured and assigned, allowing for a precise determination of the corresponding energy level positions of CO-para-H2. The data obtained enable further radio astronomical searches for this molecular complex and provide a sensitive test of the currently best available intermolecular potential energy surface for the CO-H2 system.

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