Abstract
Pure rotational transitions of the Kr–OH van der Waals complex and its deuterated analog in the ground electronic state with resolved fine and hyperfine structures were observed by Fourier-transform microwave spectroscopy. Three-dimensional potential energy surfaces of Kr–OH, average V Π and difference V 2 potentials, were determined by a simultaneous analysis utilizing all the observed data for 82Kr–OH, 84Kr–OH, 86Kr–OH, and 84Kr–OD, where all the freedom of motions for an atom–diatom system in the Jacobi coordinates, R, θ, and r, were considered. The dependence of the intermolecular interaction energy on the bond length of the OH monomer is compared with those of Ar–OH and Ne–OH.
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