Role of viscosity in the magnetic field effect on pyrene–DMA exciplex emission at different permittivities

Abstract

Effect of viscosity variation on the magnetic field effect in pyrene-N,N-dimethylaniline exciplex luminescence has been studied at different permittivity values. The data is compatible to the model of Krissinel et al. (1999) [10] reported earlier to explain the effect probing the escape yield of radical pairs. It is shown that the data can also be explained on the basis of a simple model. It is interesting to note that the present letter also demonstrates the positive slope of MFE with diffusivity at extremely high viscous condition as predicted by Krissinel et al. (1999) [10] which has not been observed in earlier experiments.