Abstract
High intense UV–VIS up-conversion luminescence from orthorhombic K2YF5 fluoride crystals doubly doped with Yb3+ and Er3+ has been obtained under near-infrared excitation at 980nm. Fluoride crystals containing high Yb3+ concentrations, namely 20; 40 and 99at.%, and low Er3+ concentrations have been synthesized under hydrothermal conditions. The role of the Yb3+ ions in the mechanism of the up-conversion process is clearly disclosed with absorption and up-conversion luminescence spectra from which one can see that high intense green (520–545nm) and outstanding UV-blue (380–410nm) emissions are greatly enhanced by increasing the concentration of Yb3+ ions whose aggregate acts as an infrared collector harvesting long wavelength infrared photons. Outstanding total infrared to UV–VIS up-conversion efficiency of 66% has been calculated for the sample with the highest Yb3+ doping level, i.e. 99at.%. These strong UV-blue up-conversion emissions would have the potential use in enhancing spectral response of main semiconductor electrodes (such as TiO2 and Fe2O3), and these K2YbF5 crystals doped with Er3+ could be used in photo-electrochemical devices for sustainable production of hydrogen via photolysis of water, as a promising photonic approach which is currently discussed in the literature.
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