Role of Temperature and Hydrochloric Acid on the Formation of Chlorinated Hydrocarbons and Polycyclic Aromatic Hydrocarbons During Combustion of Paraffin Powder, Polymers, and Newspaper

Abstract

Formation of chlorinated hydrocarbons and polycyclic aromatic hydrocarbons (PAHs) were determined using a laboratory-scale incinerator when combusting materials at different temperatures, different concentrations of hydrochloric acid (HCl), and when combusting various types of polymers/newspaper. Polychlorobenzenes (PCBz), polychlorophenols (PCPhs), polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) and their toxic equivalency (TEQ) and PAHs were highlighted and reported. Our results imply maximum formation of chlorinated hydrocarbons at 400 degrees C in the following order; PCBz>or=PCPhs>>PCDFs>PCDDs>TEQ on a parts-per-billion level. Similarly, a maximum concentration of chlorinated hydrocarbons was noticed with an HCl concentration at 1000 ppm with the presence of paraffin powder in the following order; PAHs>PCBz>or=PCPhs>>PCDFs>PCDDs>TEQ an a parts-per-billion level. PAHs were not measured at different temperatures. Elevated PAHs were noticed with different HCl concentrations and paraffin powder combustion (range: 27-32 microg/g). While, different polymers and newspaper combusted, nylon and acrylonitrile butadiene styrene (ABS) produced the maximum hydrogen cyanide (HCN) concentration, concentrations of PCDD/FS, dioxin-like polychlorinated biphenyls (DL-PCBs), and TEQ were in a decreasing order: polyvinylchloride (PVC)<newspaper<polyethyleneterephthalate (PET)< polyethylene (PE)< polypropylene (PP)< ABS = blank. Precursors of PCBs were in a decreasing order: PP<nylon<PE<newspaper<ABS<PVC<blank<PET. Precursors of PCDD/Fs were in a decreasing order: newspaper <PP=nylon<PE<ABS<PVC= blank<PET. BTX formation was in a decreasing order; PE<nylon<newspaper<ABS<PP. PAHs formation were elevated with parts-per-million levels in the decreasing order of PP<nylon<PE<newspaper<blank<ABS< PET<PVC.