Abstract
The transformation of chloromethane into light olefins (C2–C4) has been studied both on HZSM-5 catalysts with different SiO2/Al2O3 ratios (30, 80, and 280) and on SAPO-n catalysts (SAPO-34 and SAPO-18) in order to analyze the role of shape selectivity and acidity in the kinetic behavior. The catalysts have been prepared by agglomerating these acid functions with bentonite and α-Al2O3, and the kinetic runs have been performed in a fixed bed reactor under the following operating conditions: 350 and 450 °C; space time, 2.35, 5.89, and 14.99 gcat h (molCH2)−1; and time on stream, 255 min. A comparison of the reaction indices (conversion of chloromethane, selectivity to light olefins, and propylene fraction) at zero time and throughout time on stream using the different catalysts has allowed establishing, on the one hand, the significance of the shape selectivity and acidity of these catalysts (which are more influential in this reaction than in the transformation of methanol), and on the other, the need for a...
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
