Abstract
ABSTRACTThis work focuses on the evaluation of modified surfaces on Ti produced by powder metallurgy. These newly designed surface modifications are achieved by deposition and diffusion of a stable aqueous suspension prepared in one case from micro-sized Nb powder (Ti β-stabilizer element) and in another case from Nb plus the addition of ammonium chloride, NH4Cl, (thermo-reactive diffusion process). Different design parameters such as diffusion element (Nb or Mo), state of the Ti substrate (green or sintered) and the treatment process (diffusion or thermo-reactive diffusion) lead to all the surface-modified materials, GreenTi–Nb, SintTi–Nb and Ti–NbNH4Cl, GreenTi–Mo, SintTi–Mo and Ti–MoNH4Cl. The modified Ti surfaces present a gradient in composition and microstructure (β / α+β / α phases) resulting in an improvement in some of their mechanical properties: (1) higher micro-hardness in all the modified materials and (2) lower elastic modulus (more similar to that of the human bone) in those without NH4Cl.Invited keynote papers from EuroPM2017, Milan.
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