Abstract

V-based kagome materials AV3Sb5 (A = K, Rb, Cs) have attracted much attention due to their novel properties such as unconventional superconductivity, giant anomalous Hall effect, charge density wave (CDW) and pair density wave. Except for the 2a 0 × 2a 0 CDW (charge density wave with in-plane 2 × 2 superlattice modulation) in AV3Sb5, an additional 1 × 4 (4a 0) unidirectional stripe order has been observed at the Sb surface of RbV3Sb5 and CsV3Sb5. However, the stability and electronic nature of the 4a 0 stripe order remain controversial and unclear. Here, by using low-temperature scanning tunneling microscopy/spectroscopy (STM/S), we systematically study the 4a 0 stripe order on the Sb-terminated surface of CsV3Sb5. We find that the 4a 0 stripe order is visible in a large energy range. The STM images with positive and negative bias show contrast inversion, which is the hallmark for the Peierls-type CDW. In addition, below the critical temperature about 60 K, the 4a 0 stripe order keeps unaffected against the topmost Cs atoms, point defects, step edges and magnetic field up to 8 T. Our results provide experimental evidences on the existence of unidirectional CDW in CsV3Sb5.

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