Abstract

Robust and accurate state of charge estimation for LiFePO4 batteries has tremendous significance, since they are constituted the basis of reliable operation for battery management system. However, the nature flat voltage curve poses challenges in both the accuracy and robustness of state of charge estimation. Here, we present a state of charge estimation framework for LiFePO4 batteries with integrating physics calculation, adaptive Kalman filter, and machine learning, where nonlinearity of flat voltage curve can be captured with strong robustness by optimized machine learning. To address the parameter sensitivity problem for dynamic neural network, the sine cosine algorithm is adopted to obtain the optimal parameters. Then, the offline training model is established based on nonlinear autoregressive models with exogenous inputs and sine cosine algorithm, and the adaptive Kalman filter is selected for online estimation. The observed data from 26,650 and 18,650 LiFePO4 batteries at 25 and 40 °C has been used to verify the accuracy and robustness of the proposed method under four working conditions. Compared to the existing methods, the proposed method can achieve strong robustness and higher accuracy in state of charge estimation with a maximum relative error below 2 %.

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