Abstract

Liquid metal batteries (LMBs) are alternatives to conventional lithium-ion batteries due to their specific benefits including high current density and long cycle life. Accurate state of charge (SOC) estimation is an important evaluation index for the battery management system (BMS), which is of great significance to ensure the safe operation of batteries. However, the estimation accuracy of SOC is influenced by many factors, including self-aging and external operating environment changes. Therefore, an online battery model with real-time parameter updates is necessary for accurate SOC estimation. In this paper, a novel dual fuzzy-based adaptive extended Kalman filter (DFAEKF) method is proposed for the SOC estimation of LMBs. Firstly, a second-order RC equivalent circuit model is established to describe the battery's behavior. The forgetting factor recursive least squares (FFRLS) is utilized to identify the model parameters and reconstruct the battery open circuit voltage (OCV). Secondly, the dual adaptive extended Kalman filter (DAEKF) is derived from the battery model. And an intelligent noise estimator is designed based on a fuzzy inference system, which adaptively adjusts the length of the residual innovation sequence (RIS), to update the noise covariance. Finally, the DFAEKF algorithm is proposed for the battery SOC and parameter co-estimation. The online estimated ohmic resistance is employed to calculate the state of health (SOH) of the battery. The proposed DFAEKF is verified through different experiments and compared to conventional algorithms. Experimental results show that the DFAEKF has higher accuracy (error < 1 %) and stronger robustness. The proposed method can also be applied to other model-based state estimation areas.

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