Robust functionalized cellulose-based porous composite for efficient capture and ultra-fast desorption of aqueous heavy metal pollution

Abstract

The heavy metal pollution control industry requires convenient and cost-effective solutions to address complex aqueous environment. Adsorption method can be an effective strategy to realize these goals. Considering the importance of environmental and sustainable development strategies, there is an urgent need to develop efficient, green and non-toxic heavy metal adsorbents. In this work, a robust aminated cellulose-based porous adsorbent (PGPW) was developed from delignified wood and amino-rich polymer using a solvent-free, mild, simple and efficient preparation method. Such adsorbent exhibited excellent adsorption capacity (188.68 mg g−1) for Cu(II), and its adsorption behavior was consistent with pseudo-second order kinetic and Langmuir isotherm models. Notably, PGPW with superior compressibility could be squeezed to achieve rapid desorption and reach equilibrium within 5 min, while still retaining 87 % adsorption efficiency after 50 cycles. In addition, PGPW showed remarkable selectivity towards various coexisting ionic systems and demonstrated a considerable adsorption capacity in natural water applications. The adsorption mechanism of heavy metal ions on porous adsorption material was elucidated. This approach provides a simple, gentle and sustainable strategy for preparing functionalized wood-based composites with efficient adsorption and ultra-fast desorption of heavy metal ions.