Abstract

Sustainable growth can be achieved by recycling waste material into useful resources without affecting the natural ecosystem. Among all nanomaterials, carbon nanomaterials from biowaste are used for various applications. The pyrolysis process is one of the eco-friendly ways for synthesizing such carbon nanomaterials. Recently, polymer nanocomposites (PNCs) filled with biowaste-based carbon nanomaterials attracted a lot of attention due to their enhanced mechanical properties. A variety of polymers, such as thermoplastics, thermosetting polymers, elastomers, and their blends, can be used in the formation of composite materials. This review summarizes the synthesis of carbon nanomaterials, polymer nanocomposites, and mechanical properties of PNCs. The review also focuses on various biowaste-based precursors, their nanoproperties, and turning them into proper composites. PNCs show improved mechanical properties by varying the loading percentages of carbon nanomaterials, which are vital for many defence- and aerospace-related industries. Different synthesis processes are used to achieve enhanced ultimate tensile strength and modulus. The present review summarizes the last 5 years’ work in detail on these PNCs and their applications.

Highlights

  • The composites prepared in an appropriate way by reinforcing fillers, such as Sugarcane bagasse (SCB) ash, biochar, and carbon black derived from waste SCB, improves the mechanical properties [120]

  • Sustainable growth of the world can be achieved by recycling waste material into useful resources without affecting the natural ecosystem

  • The biowaste generated in millions of tonnes must be reutilized in the conversion process of waste to wealth

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Summary

Introduction

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. Fillers play a significant role in the formation of PNCs, as they provide excellent mechanical, electrical, and optical properties. The microsized fillers, such as glass fibre, talc, calcium carbonate, charcoal powder, and ash powder, are extensively used to enhance the strength of host materials. The synthesis of nanocarbons from biomass involves extraction of carbon from natural and inexpensive bioresources, such as lignin, glucose, and cellulose-based materials Various biowaste materials, such as coffee grounds [8], areca nut [9], onion peel [10], garlic peel [11], banana peel [12], walnut shell [13], wheat husk [14], corn cob [15], and fish scale [16] are used as precursors for the generation of carbon nanomaterials (CNMs). Polymer composites reinforced with CNMs derived from different biowaste materials from recent research activities are critically reviewed. Mechanical properties, such as tensile strength, modulus, and fractural behaviour of PNCs are summarized

Biowaste-Based Carbon Nanomaterials
Classification of Biowaste Material
Carbon Nanomaterial Synthesis and Its Applications
Properties and Applications of Polymer Composites
Factors Influencing Reinforced Composites
Well Dispersion and Reduced Agglomerations
Interfacial Interaction between Polymer and Nanofiller
Synthesis of Polymer Nanocomposites
Solvent Processing
Melt Extrusion
CNM-Reinforced Composites from Various Biowastes
Importance of Coconut Shell-Derived Nanoparticles
Synthesis of Carbon Nanoparticles from Coconut Shell Powder
Characterization of Carbon Nanoparticles Obtained from CS Powder
Synthesis of Carbon–Polymer Nanocomposites
Characterization of Nanocomposites
Method
Importance of Wood Apple Shell-Derived Nanoparticles
Characterization of Carbon Black Obtained from Wood Apple Shell
Importance of Bamboo Biochar-Derived Nanoparticles
Synthesis of Carbon Nanoparticles from Bamboo Biomass
Characterization of BC Particles Obtained from Bamboo Biomass
Synthesis of Carbon–Polymer Nanocomposite Films
Importance of Rice Husk-Derived Nanoparticles
Synthesis of Biochar from Rice Husk
Characterization of Carbon Nanoparticles Obtained from RH Biochar
Importance of Sugarcane Bagasse Nanoparticles
Synthesis of Carbon Black from Sugarcane Bagasse Waste
Characterization of Carbon Black Produced from Sugarcane Bagasse
Importance of Groundnut Shell-Derived Nanoparticles
Synthesis of Carbon Nanoparticles from Groundnut Shell
Importance of Oil Palm Leaves and Empty Fruit Bunch-Derived Nanoparticles
Synthesis of Carbon Nanoparticles from Oil Palm Leaves
Characterization of Carbon Nanoparticles Obtained from Oil Palm Leaves
Findings
Conclusions and Future Perspectives
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