Abstract
Dipotassium [nickel(II) zirconium(IV)] tris(orthophosphate) was prepared from a self-flux in the system K2O–P2O5–NiO–K2ZrF6. The title compound belongs to the langbeinite family and is built up from two [MO6] octahedra [M = Ni:Zr with mixed occupancy in ratios of 0.21 (4):0.79 (4) and 0.29 (4):0.71 (4), respectively] and [PO4] tetrahedra interlinked via vertices into a 3 ∞[M 2(PO4)3] framework. Two independent K+ cations are located in large cavities of the framework, with coordination numbers to O2− anions of nine and twelve. The K, Ni, and Zr sites are located on threefold rotation axes.
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More From: Acta crystallographica. Section E, Structure reports online
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