Tris(tetrahydrofuran-κO)tris[tris(thiophen-2-yl)methanolato-κO]terbium(III) tetrahydrofuran monosolvate

Michael Veith,Celine Belot,Volker Huch

doi:10.1107/s160053681104623x

Abstract

In the mononuclear title compound, [Tb(C13H9OS3)3(C4H8O)3]·C4H8O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octahedral geometry. One of the thienyl groups and the bound THF are disordered with 0.5:0.5 occupancy. The free THF is disordered around the threefold axis.

Highlights

Institut für Anorganische Chemie, Universität des Saarlandes, Postfach 151150, 66041 Saarbrücken, Germany, and Leibniz Institute for New Materials, 66123
In the mononuclear title compound, [Tb(C13H9OS3)3(C4H8O)3]C4H8O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octahedral geometry
The free THF is disordered around the threefold axis

Summary

Crystal data

Institut für Anorganische Chemie, Universität des Saarlandes, Postfach 151150, 66041 Saarbrücken, Germany, and Leibniz Institute for New Materials, 66123. Key indicators: single-crystal X-ray study; T = 132 K; mean (C–C) = 0.006 Å; disorder in main residue; R factor = 0.035; wR factor = 0.085; data-to-parameter ratio = 23.9. In the mononuclear title compound, [Tb(C13H9OS3)3(C4H8O)3]C4H8O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octahedral geometry. One of the thienyl groups and the bound THF are disordered with 0.5:0.5 occupancy. The free THF is disordered around the threefold axis

Related literature

Bruker APEXII CCD diffractometer

Special details