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https://doi.org/10.1021/acs.joc.1c01636
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Cite Journal: The Journal of Organic Chemistry |  Publication Date: Sep 7, 2021 |
 Citations: 7 |
Affiliation: Keio University
Anti-Markovnikov hydroamination of both aliphatic and aromatic terminal alkynes with primary amines was achieved using an 8-quinolinolato rhodium catalyst to form aldimines and enamines in high yields. This catalytic system realized high functional group tolerance including hydroxy, bromo, cyano, and thioester groups.
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