Rheology of hydrated plagioclase at lower crustal conditions: Cataclasis, creep and transformational plasticity

Abstract

Plagioclase feldspar is one of the main rock-forming minerals of the lower continental crust. Assessing its rheology is therefore of particular importance for understanding the mechanical processes acting in convergence zones, where pressure and strain rate increases are often associated with metamorphic reactions and fluid fluxes. In this prospect, we performed axial shortening experiments on “as-is” (∼0.05 wt% H2O) and water-added (∼0.29 wt% H2O) natural plagioclase samples in a Griggs-type apparatus equipped with an acoustic emission monitoring system. Samples were deformed at ∼ 10−6 and ∼ 10−5 s−1, 700–800 °C, and 1.0 GPa in the plagioclase stability field. Experiments have also been performed at 1.5 GPa in order to study the rheological impact of the breakdown reaction Ca-rich plagioclase + water → zoisite + kyanite + quartz + Na-rich plagioclase. Mechanical data indicate that at the conditions studied, the rheology of plagioclase is strongly affected by water content. Microstructural observations confirm that under dry conditions, plagioclase aggregates deform by cataclastic flow. Under wet conditions, dislocation creep appears to be the dominant deformation mechanism, and plagioclase rheology is best described by the following equation, where strain rate, in s−1, is expressed as:ε·=Aσ3.0exp(−(168kJ/mol)/R/T), where σ is the stress in MPa, R is the gas constant, T is the temperature in K, and the pre-exponential term A=10−3.9MPa−3.0s−1. At 1.5 GPa, the reaction is faster under wet conditions but the rheology observed remains identical to that of wet plagioclase in its stability field. In the low water content experiments, plagioclase breakdown induces transient weakening due to fast zoisite nucleation and significant reaction volume change.