Rheology Characterization of Ionic Liquids under High Pressure and High Temperature

Abstract

Ionic liquids (ILs) are liquid salts that exist at or below ambient temperatures and are composed of ion pairs. They offer promising alternatives to toxic, hazardous, highly flammable, and volatile solvents in various applications such as solution preparation, dispersion, gel formation, composites, and polymer melts. ILs possess unique and interesting characteristics, including excellent chemical and thermal stability and low vapor pressures. Understanding the rheological properties of ILs is essential to optimizing IL performance. This paper presents a comparative analysis of the rheological properties of two ionic liquids, N-Hexylpyridinium tetrafluoroborate (HPyBF4) and N-Hexylpyridinium bromide (HPyBr), under different shear rates, temperatures, and pressures. Rheological measurements were performed under varying controlled pressure and temperature conditions. The experimental investigation covered a pressure range of 689 to 12,411 kPa [100–1800 psi] and a temperature range from room temperature up to 522 kelvin (K) [480°F]. The primary objective is to explore and compare the flow behavior and viscoelastic characteristics of HPyBF4 and HPyBr under high-pressure and high-temperature conditions. The experimental data showed that HPyBF4 and HPyBr exhibited shear-thinning behavior, and pressure had an insignificant effect on rheology compared to the temperature effect. Under the same testing conditions, HPyBr showed higher shear stress and viscosity than HPyBF4. This research significantly contributes to the improved understanding of the rheological behavior of these specific ionic liquids and their suitability for diverse industrial and scientific applications, particularly in high-pressure and high-temperature environments.