Abstract

The possibilities and conditions of correlation are determined for the principal rheological characteristics of single-phase polymer systems measured for one-dimensional shear deformation in steady-state flow regimes, on transition from rest to steady-state flow, and in harmonic vibration regimes. Special significance attaches to the quantitative results of measuring the high-elastic properties of the polymer systems. It is shown that the Lodge theory, describing the flow behavior of high-elastic media, is well-founded in the linear region of deformation, i.e., for the limiting case of shear rates and shear stresses tending to zero, whereas the Mooney-Rivlin-Weissenberg theories are not in accord with the experimental data even in this limiting deformation regime.

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