Abstract
Polyalphaolefins (PAOs) are regarded as superior lubricants, but the biodegradability of the very low-viscosity PAO2/PAO4 has been ignored over a long history, despite being inherently biodegradable (PAO2/PAO4 biodegradation rate >20% by OECD guidelines). Previous studies typically concentrated on a single viscosity grade of PAO with additives, seldom engaging in comparative research efforts involving multiple low-viscosity grades of neat PAO concurrently. This study compares PAO2/PAO4 with non-biodegradable PAO6 regarding rheology and lubricating film formation. PAO2/PAO4 are Newtonian fluids with ≤10% viscosity fluctuation at high shear rates, while PAO6 shows a viscosity fluctuation of ≥15% at high shear rates. Viscosity–temperature equations are derived. An optical interference method measures lubricating film thickness. PAO2/PAO4 films are less sensitive to speed/load changes. PAO2 mainly works in boundary lubrication. Interference images show possible unique EHL characteristics of PAOs. The Hamrock–Dowson formula overestimates PAO6 film thickness at high speeds.
Published Version
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