Abstract

To improve the performance of petroleum asphalt, bio-char was used as a modifier for a petroleum asphalt binder, in this study. The rheological properties of bio-char modified asphalt binders were compared with different particle sizes and contents, with one control and one flake graphite modified asphalt binder. Specifically, the bio-char modifiers with two particle sizes (ranging from 75 μm–150 μm and less than 75 μm) and three contents of 2%, 4%, and 8% were added into the asphalt binder. A flake graphite powder with particle sizes less than 75 μm was used as a comparison modifier. The Scanning Electron Microscopy (SEM) image showed the porous structure and rough surface of bio-char as well as dense structure and smooth surface of flake graphite. A Rotational Viscosity (RV) test, Dynamic Shear Rheometer (DSR) test, aging test, and Bending Beam Rheometer (BBR) test were performed to evaluate the properties of bio-char modified asphalt in this study. Both modifiers could improve the rotational viscosities of the asphalt binders. The porous structure and rough surface of bio-char lead to larger adhesion interaction in asphalt binder than the smooth flake graphite. As a result, the bio-char modified asphalts had better high-temperature rutting resistance and anti-aging properties than the graphite modified asphalt, especially for the binders with the smaller-sized and higher content of bio-char particles. Furthermore, the asphalt binder modified by the bio-char with sizes less than 75 μm and about 4% content could also achieve a better low-temperature crack resistance, in comparison to other modified asphalt binders. Thus, this type of bio-char particles is recommended as a favorable modifier for asphalt binder.

Highlights

  • Bio-char has been studied since the 20th century [1]

  • The rheological properties were evaluated in the laboratory, and the effect of microscopic morphology, the particle size and the content of bio-char in the properties of bio-char modified asphalt binder, were researched in this study

  • The Dynamic Shear Rheometer (DSR) test can be conducted to determine the rheological behavior of asphalt binders in varying temperature and frequency conditions [40,41]

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Summary

Introduction

Bio-char has been studied since the 20th century [1] It is a product rich in carbon consisting of organic compounds, generally produced by pyrolysis technology [2,3]. It is likely that bio-char can be used as a modifier for asphalt modification, to reduce environmental impacts and human health concerns. With the addition of carbon fiber, the high-temperature properties and rutting resistance of asphalt binder, as well as the alleviation of the aging and oxidation processes, were improved [26,27]. A limited number of studies have focused on the performance evaluation of modified asphalt by using bio-char from waste wood as a modifier. The rheological properties of asphalt binder modified by bio-char, with different particle sizes, were evaluated in this study

Motivation and Objectives
Graphite and Preparation of Graphite Modified Asphalt
Bio-Char and Preparation of Bio-Char Modified Asphalt
Experimental Program
Aging Test
Microscopic
Rotational
Anti-Aging Property Analysis
Rutting Resistance Analysis
High Critical Temperature Analysis
It is obvious that bio-char asphalts based on high-temperature
Low-Temperature Cracking Resistance Analysis
Low Critical Temperature Analysis
75 The μm
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