Abstract

The rheology of PP filled with three different types of fillers, namely synthetic sodium aluminium silicate (SSAS), aluminium silicate (AS) and calcium carbonate (CaCO3), at concentrations up to 40% was studied. Variation of shear and extensional viscosity was evaluated for all the compositions. When filler loading was less than 20%, the shear viscosity at low shear rates was less than that of virgin PP. Flow curves are described by the Ellis model. The onset of non-Newtonian shear thinning behaviour is related to parameter η10/τ1/2. Although fillers are white, they imparted a yellowish tone at lower loadings. At higher loadings, this yellowing effect was masked, yielding a lower yellowness index.

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