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https://doi.org/10.1016/s0040-4020(01)81193-5
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Cite Journal: Tetrahedron |  Publication Date: Jan 1, 1992 |
 Citations: 21 |
Affiliation: University of Perugia
Unsaturated α-diazocarbonyl compounds undergo intramolecular cyclopropanation or carbon-hydrogen bond insertion when catalyzed by Rh 2(OAc) 4: α-diazo ketones react preferentially with carbon-carbon doubled bond, whereas closely related α-diazo-β-keto-esters insert into carbon-hydrogen bond.
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