Abstract
Summary. The phase diagram of the binary system NaF– NaBF4 was determined using the thermal analysis method. Subsequent coupled analysis of the thermodynamic and phase diagram data was carried out to calculate the thermodynamically consistent phase diagram. The system NaF–NaBF4 forms a simple eutectic phase diagram with the calculated coordinates of the eutectic point: 8.1 mol% NaF, 91.9 mol% NaBF4, and 385.7 � C. The probable inaccuracy in the calculated binary phase diagram is 9 � C.
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