Abstract
Exchange between Ar and Ar′ groups in trans-Ni(Ar)(SAr′)(PEt3)2 and cis-Ni(Ar)(SAr′)(dmpe)[dmpe = 1,2-bis(dimethylphosphino)ethane] takes place to give a mixture of Ni(SAr)(Ar′)L2 and Ni(Ar)(SAr′)L2via reversible reductive elimination and oxidative addition of diaryl sulphides involving C–S bond cleavage and formation at the Ni centre.
Published Version
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