Abstract
In the reaction A + B C, where A and B are ionic reactants having opposite charges, a B molecule approaching an A will experience a switching of the interaction potential when the A molecule is captured by one of the other B molecules in the medium. In the reversible case, the former B molecule still has a chance to react with the A, so that one needs to take into account the switched interaction between the reactant B and the product C as well as that between the reactants to treat the kinetics accurately. It is shown that this kind of interaction potential switching affects the relaxation kinetics in an intriguing way as observed in a recent experiment on an excited-state proton transfer reaction. 歯漀 Ѐ瑫牳 ܀ 佂䝈䉑搀Ā܀ 硰�⨀ Ā灳欀 Ѐ歳瑴 ろ�⨀ 䉇䡂儀나�⨀ 렲ﶖ⨀ ﶖ⨀ �⨀ ㄲ㈵ⴱ㈷㖟�⨀ 歳牭⨀ 킃�⨀ ƗԀ⨀ q�⨀ Ā�⨀ 桶�⨀ ᢄ�⨀ �⨀ ꢂ�⨀ ѫ獲洀 Ѐ歯捳 ﶖ⨀ ᤁ 돐쁯�⨀ 歳牭떭铫나뗭閙谀 Ԁ歡獩挀܀ Ԁ歩潭搀܀ Ԁ歡楣椀 Ѐ整物 ࠀ 歳牭獰攱 Ѐ瑫扳 ܀ Ԁ武浡 鳪떭铫나뗭閙谀 Ѐ歧桰 Ѐ武牭 섂 돀遠�⨀ 堘�⨀ 肴�⨀ 僐�⨀ 餂 돐 ࠴ﶖ⨀ 墵�⨀ ／ࠀ胐�⨀ 夂 덐 ꠀ s牭 Ԁ慥 s�⨀ 歳獡 欁煭 k獲洀 獯污爀1ﶖ⨀ 1ﶖ⨀ �⨀ o牥慮⁓c楥瑹r⁒潣欠e捨慮楣~�⨀ 㠀 ࢫ�⨀ ₆�⨀ ⢮�⨀ Ԁ 正猀 Ѐ歳獳 ܀ Ԁ歩捥洀܀ 戀 Ȁ浩猀䡴�⨀ Ȁ܀ 灡欀 Ѐ殁p ك佌䍌䄁戀步桳 ࠀ 쀟ﶖ⨀ ﶖ⨀ †ﶖ⨀ ꧬ鮔萀 Ԁ歳浭攀 Ѐ步獫 Ѐ歩慳 Ѐ歡潭 佂䝈䉑 퇪 돀遠�⨀ ꁠﲖ⨀ �⨀ �⨀ 돐 ゅ�⨀ ��⨀ 㢅�⨀ 뤏 덐 䢅�⨀ 렏 頏
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
