Abstract
As part of the compilation of a database of substituent parameters for the prediction of retention indices in reversed-phase high-performance liquid chromatography, the reproducibility of retention measurements over a two-year period has been determined. Care was taken to ensure constant mobile phase and operating conditions and all the work was carried out using a single batch of stationary phase. Retention indices, based on the alkyl aryl ketones, were found to be much more consistent than capacity factors for recording retentions.
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