Abstract

The valence-band resonant photoemission spectra (RPES) of LiMn2O4 have been measured throughout the Mn3p absorption edge. Based on the RPES data, the contribution of Mn3d states to the valence band of LiMn2O4 has been described and, consequently, the detailed hybridization between O2p and Mn3d states in the valence-band was determined.

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