Abstract
We discuss the possibility of using the energy of the transmitted electron (ϵ) as a control parameter in electron transfer (ET) reactions. The change in response of the system is entirely contained, within the simplest model, in the effective electronic coupling, which exhibit sharp changes in the resonance region and near its minima as a function of ϵ. The positions of the minima are strongly influenced by the molecular geometry. To calculate the effective coupling, we use a Green's function approach. The electronic structure is calculated within an extended Hückel model. We show the interference and resonance behavior appears for a very simple a four-site model with multisite interactions. The interference effects disappear in a tight binding model of the same system. Application to a molecular system dramatically shows these effects.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Photochemistry & Photobiology, A: Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
