Removal of heavy metals from sewage sludge by chemical leaching with biodegradable chelator methyl glycine diacetic acid

Abstract

The heavy metals (HMs) contained in sewage sludge are some of the largest obstacles that hamper the usage of sewage sludge in land application (e.g. fertilizer, soil improver). The conventional chelators, e.g., ethylenediaminetetraacetic acid (EDTA), were effective in the remediation of HMs polluted sewage sludge, but suffered from an evident drawback of low biodegradability. Therefore, the applicability of a new biodegradable chelator, methyl glycine diacetic acid (MGDA), to extract HMs from sewage sludge was carried out and compared with EDTA. The experimental parameters affecting the performance of MGDA were optimized. Leaching results showed that in general, MGDA exhibited higher Zn leaching efficiency and similar Cu, Ni and Cr leaching efficiencies with EDTA at same pH and dosage conditions. The maximum Zn, Cu, Ni and Cr leaching efficiencies of MGDA were 94.1% ± 4.5%, 58.2% ± 3.1%, 78.2% ± 2.3% and 54.6% ± 2.5%, respectively. The leaching efficiency plateaued within a reaction time of 4 h, but that of Cu and Ni showed a slightly decreasing trend during hours 4 to 10. In raw sewage sludge, the Zn and Cu were mainly presented in the organically bound fraction, i.e., 45.3 ± 3.2% of total Zn and 48.3 ± 1.4% of total Cu. The addition of MGDA and EDTA caused obvious distribution transformations in Zn and Cu from the organically bound fraction to soluble fraction. According to the reduced partition index calculation, the mobility of Zn, Cu, Ni, and Cr was not significantly lowered after the MGDA treatment. However, the HMs secondary pollution risk of the sludge was reduced due to the drop of the total HMs content after chelator leaching. Findings from this study suggest that MGDA could be a potential environment-friendly alternative for refractory chelators (e.g. EDTA) in the decontamination of HMs from sludge.