Removal of cesium from low-level radioactive wastewaters using magnetic potassium titanium hexacyanoferrate

Abstract

The rapid development of nuclear energy in China has led to an increase in attention to the treatment of low-level radioactive wastewaters (LLRWs). One of the important contaminants is radioactive Cs. The removal of trace amounts of 134Cs and 137Cs can be achieved by means of a selective adsorption process. One of the possibilities is the application of potassium titanium hexacyanoferrate. In this paper, a novel magnetic potassium titanium hexacyanoferrate (M-PTH) material was prepared. The batch experiments demonstrate a selective adsorption of Cs over a wide pH range from 1 to 10. The co-existing nonradioactive ions can affect the adsorption of Cs. By increasing the Na+ and K+ concentration from 0.001 to 0.1M, the distribution coefficient (Kd) of Cs drops slowly within the ranges of 7.28×104 to 1.10×104mL/g and 1.25×105 to 1.49×104mL/g, respectively. The adsorption isotherm coincides well with the Langmuir model. The thermodynamic study reveals an endothermic and spontaneous process. The kinetic performance follows the pseudo-second-order adsorption model, with intra-particle diffusion as the rate-controlling step. Based on the characteristics of M-PTH, a sequencing batch reactor (SBR) was considered to be suitable for the treatment of LLRWs containing radioactive Cs. Up to a total throughput of 70 batches, the decontamination factor (DF) can be kept at 1000. The volume ratio of treated solution and exhausted adsorbent was almost 7000.