Removal effect of Cr (VI) by adsorbent made from sewage sludge

Abstract

Adsorbent made from sewage sludge is used to remove the Cr (VI) in wastewater. In this paper, the adsorption capacity, adsorption mechanism and regeneration of the adsorbent are studied. A systematic research is carried out to investigate the influence of adsorption capacities in various conditions, such as contact time, pH and initial dosage of adsorbent. The results show that: the equilibrium time is 6 h; the optimal pH is 2.5. The adsorption capacity increases as the initial concentration increase and as the dosage of activated carbon decrease. The data of adsorption capacity are more fit in Langmuir isotherms. The adsorption follows a pseudo-second-order kinetic model perfectly. From this research, the adsorption rate controlling step is film diffusion when the Cr (VI) concentration is low; otherwise, the adsorption rate controlling step is the diffusion among particles. The results of regeneration of saturated adsorbent show that the saturated adsorbent can be perfectly regenerated using alkali treatment. The regeneration ratio of the saturated adsorbent can reach more than 90% with proper concentration of alkali.