Abstract

Ethylene molecules are considered to oligomerize in the interlayer nano-space of ternary graphite intercalation compounds (GICs), CsC 24(C 2H 4) x ; however, the mechanism and the degree of oligomerization have not yet been clarified. In the present study, the released gases from CsC 24(C 2H 4) 1.4 at high temperatures were investigated by TG/GC–MS under helium atmosphere. The detection of alkanes (C3–C20) by TG/GC–MS analysis in both the trap and direct modes supported the existence of the oligomers in the nano-space. Other gases such as water vapor, methane, etc., were also detected.

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