Abstract
Abstract The structure and bulk reactivity of phases belonging to V-O and Mo-O systems are examined from the standpoint of their surface “crystal field” needed in selective mild oxidation of hydrocarbons (C2-C8). The reactivity (bulk and catalytic surface) of these M-O systems is modified by addition of another cation M' in variable amounts. It is shown that improved performance results when M', as a promoter or inside a support, contributes to stabilize a particular selective phase MO, or when a new compound MM'O with its own structure, reactivity and catalytic properties is obtained.
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